In one kind of chemical reaction, unconverted reactants change into converted reactants.The fractiona of reactants that have been converted increases at a rate proportional to the product of the fraction of converted reactants and the fraction of unconverted reactants.Which equation describes this relationship?Choose 1 answer:(A) dtda=1−aka(B) dtda=ka2(C) dtda=ka(1−a)(D) dtda=a(1−a)k
Q. In one kind of chemical reaction, unconverted reactants change into converted reactants.The fraction a of reactants that have been converted increases at a rate proportional to the product of the fraction of converted reactants and the fraction of unconverted reactants.Which equation describes this relationship?Choose 1 answer:(A) dtda=1−aka(B) dtda=ka2(C) dtda=ka(1−a)(D) dtda=a(1−a)k
Denote Fraction of Reactants: Let's denote the fraction of reactants that have been converted by a. According to the problem, the rate of change of a with respect to time t, which is dtda, is proportional to the product of the fraction of converted reactants a and the fraction of unconverted reactants 1−a. The constant of proportionality is k. Therefore, the equation that describes this relationship is dtda=k⋅a⋅(1−a).
Rate of Change Equation: We can now compare the given options with our derived equation. Option (A) dtda=1−aka does not match because it suggests the rate is inversely proportional to the fraction of unconverted reactants, which is not what the problem states.
Comparison with Options: Option (B) dtda=ka2 suggests the rate is proportional to the square of the fraction of converted reactants, which again is not what the problem states.
Option (A) Analysis: Option (C) dtda=ka(1−a) matches our derived equation exactly, indicating that the rate of conversion is proportional to both the fraction of converted reactants and the fraction of unconverted reactants.
Option (B) Analysis: Option (D) dtda=a(1−a)k suggests the rate is inversely proportional to the product of the fraction of converted and unconverted reactants, which is incorrect according to the problem statement.
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